Synthesis and Application of New Dipyrido-annulated <i>N</i>-Heterocyclic Carbene with Phosphorus Substituents

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  • Shin-ichi Fuku-en
    Department of Chemistry, Graduate School of Science, Hiroshima University
  • Junki Yamamoto
    Department of Chemistry, Graduate School of Science, Hiroshima University
  • Satoshi Kojima
    Department of Chemistry, Graduate School of Science, Hiroshima University
  • Yohsuke Yamamoto
    Department of Chemistry, Graduate School of Science, Hiroshima University

抄録

<jats:title>Abstract</jats:title> <jats:p>A new dipyrido-annulated N-heterocyclic carbene with phosphorus substituents at the 4 and 8 positions and the corresponding Rh(I) and Rh(III) complexes prepared from the carbene are reported. The X-ray structure of the Rh(I) complex 11 suggested the presence of strong interactions between the phosphorus atoms and Rh(I), in contrast to the previously reported sulfur-substituted system. The new carbene ligand shows promise as a useful carbene-centered pincer ligand with a fixed scaffold for other metal complexes.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 43 (4), 468-470, 2013-12-20

    Oxford University Press (OUP)

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