Silicon-based C–N Cross-coupling Reaction

• Kenta Shimizu

  Department of Applied Chemistry, Chuo University

• Yasunori Minami

  Research and Development Initiative, Chuo University

• Osamu Goto

  Tsukuba Research Laboratory, Sumitomo Chemical

• Hideyuki Ikehira

  Organic Synthesis Research Laboratory, Sumitomo Chemical

• Tamejiro Hiyama

  Research and Development Initiative, Chuo University

Abstract

Palladium-catalyzed C–N bond-forming cross-coupling reaction of N-trimethylsilylamines with aryl bromides and chlorides is found to proceed in the presence of a fluoride activator in 1,3-dimethyl-2-imidazolidinone (DMI), giving triarylamines in excellent yields. When aryl bromide and bis(silyl)amine were used in this reaction, double C–N bond-forming products were obtained in high yields. The present reaction was successfully applied to C–N bond-forming polymerization.

Journal

• Chemistry Letters

  Chemistry Letters 43 (4), 438-440, 2013-12-12

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360283694082188160
• NII Article ID: 130004868054
• DOI: 10.1246/cl.131075
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/43/4/438/55641482/cl.131075.pdf
• Data Source:
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