Chemisorption of Carbon Dioxide in Carboxylate-Functionalized Ionic Liquids: A Mechanistic Study

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  • Yoshiro Yasaka
    Department of Molecular Chemistry and Biochemistry, Faculty of Science and Engineering, Doshisha University
  • Masakatsu Ueno
    Department of Molecular Chemistry and Biochemistry, Faculty of Science and Engineering, Doshisha University
  • Yoshifumi Kimura
    Department of Molecular Chemistry and Biochemistry, Faculty of Science and Engineering, Doshisha University

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<jats:title>Abstract</jats:title> <jats:p>Spectroscopic investigations on the CO2 chemisorption by tetra-n-butylphosphonium formate as an example of carboxylate-functionalized ionic liquids reveal that the formation of hydrogen-bond complexes such as diformate anion supplies the driving force of the chemisorption.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 43 (5), 626-628, 2014-01-16

    Oxford University Press (OUP)

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