Chemisorption of Carbon Dioxide in Carboxylate-Functionalized Ionic Liquids: A Mechanistic Study

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Author(s)

    • Yasaka Yoshiro
    • Department of Molecular Chemistry and Biochemistry, Faculty of Science and Engineering, Doshisha University
    • Ueno Masakatsu
    • Department of Molecular Chemistry and Biochemistry, Faculty of Science and Engineering, Doshisha University
    • Kimura Yoshifumi
    • Department of Molecular Chemistry and Biochemistry, Faculty of Science and Engineering, Doshisha University

Abstract

Spectroscopic investigations on the CO<sub>2</sub> chemisorption by tetra-<i>n</i>-butylphosphonium formate as an example of carboxylate-functionalized ionic liquids reveal that the formation of hydrogen-bond complexes such as diformate anion supplies the driving force of the chemisorption.

Journal

  • Chemistry Letters

    Chemistry Letters 43(5), 626-628, 2014

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130004868113
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
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