Efficient Glycosylation Using In(OTf)<sub>3</sub> as a Lewis Acid: Activation of <i>N</i>-Phenyltrifluoroacetimidate or Thioglycosides with Halogenated Reagents or PhIO

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Author(s)

Abstract

In(OTf)<sub>3</sub> efficiently activated <i>N</i>-phenyltrifluoroacetimidate and In(OTf)<sub>3</sub> in combination with various halogenated reagents or PhIO promoted glycosylation using thioglycoside in good yields. The combination with iodine interhalogens (e.g., ICl or IBr) effectively promoted α-sialylation.

Journal

  • Chemistry Letters

    Chemistry Letters 43(6), 956-958, 2014

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130004868149
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
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