Coordination Oligomers and Polymers of an Oxazole-appended Zinc Chlorophyll Derivative

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Author(s)

    • Otsuki Joe
    • College of Science and Technology, Nihon University
    • Araki Koji
    • Institute of Industrial Science, The University of Tokyo
    • Ohara Kazuaki
    • Faculty of Pharmaceutical Science at Kagawa Campus, Tokushima Bunri University
    • Yamaguchi Kentaro
    • Faculty of Pharmaceutical Science at Kagawa Campus, Tokushima Bunri University
    • Tanaka Kentaro
    • Department of Chemistry, Graduate School of Science, Nagoya University
    • Araki Yasuyuki
    • Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
    • Wada Takehiko
    • Institute of Multidisciplinary Research for Advanced Materials, Tohoku University

Abstract

The self-assembled structures of an oxazole-appended zinc chlorophyll derivative in solution and in a crystal are reported. Cyclic oligomers formed in chloroform, while staircase-like coordination polymers formed in the crystal, both mediated by intermolecular axial coordination of the nitrogen atom in the oxazole moiety to the zinc center in another chlorophyll molecule.

Journal

  • Chemistry Letters

    Chemistry Letters 43(6), 862-864, 2014

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130004868194
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
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