Coordination Oligomers and Polymers of an Oxazole-appended Zinc Chlorophyll Derivative

  • Yoshinao Shinozaki
    College of Science and Technology, Nihon University
  • Isao Yoshikawa
    Institute of Industrial Science, The University of Tokyo
  • Koji Araki
    Institute of Industrial Science, The University of Tokyo
  • Kazuaki Ohara
    Faculty of Pharmaceutical Science at Kagawa Campus, Tokushima Bunri University
  • Kentaro Yamaguchi
    Faculty of Pharmaceutical Science at Kagawa Campus, Tokushima Bunri University
  • Shin-ichiro Kawano
    Department of Chemistry, Graduate School of Science, Nagoya University
  • Kentaro Tanaka
    Department of Chemistry, Graduate School of Science, Nagoya University
  • Yasuyuki Araki
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
  • Takehiko Wada
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
  • Joe Otsuki
    College of Science and Technology, Nihon University

Abstract

<jats:title>Abstract</jats:title> <jats:p>The self-assembled structures of an oxazole-appended zinc chlorophyll derivative in solution and in a crystal are reported. Cyclic oligomers formed in chloroform, while staircase-like coordination polymers formed in the crystal, both mediated by intermolecular axial coordination of the nitrogen atom in the oxazole moiety to the zinc center in another chlorophyll molecule.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 43 (6), 862-864, 2014-03-11

    Oxford University Press (OUP)

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