One-dimensional Anisotropic Metal–Organic Module Containing a Pt6 Chain Terminated with Redox Active Ferrocenyl Units

• Tomoaki Tanase

  Department of Chemistry, Faculty of Science, Nara Women’s University

• Chie Yamamoto

  Department of Chemistry, Faculty of Science, Nara Women’s University

• Bunsho Kure

  Department of Chemistry, Faculty of Science, Nara Women’s University

• Takayuki Nakajima

  Department of Chemistry, Faculty of Science, Nara Women’s University

Abstract

A 1D anisotropic hexaplatinum chain with redox-active terminal ligands, [Pt6(µ-H)(µ-dpmp)4(FcDipNC)2](PF6)3 (7) (dpmp: bis(diphenylphosphinomethyl)phenylphosphine, FcDipNC: 2,6-diisopropyl-4-(ferrocenylethynylene)phenyl isocyanide), was synthesized, its structure and electrochemical behavior were elucidated in comparison with those of [Pt6(µ-H)(µ-dpmp)4(DipNC)2](PF6)3 (6) (DipNC: 2,6-diisopropylphenyl isocyanide), and the module was found to undergo two stepwise two-electron oxidations.

Journal

• Chemistry Letters

  Chemistry Letters 43 (6), 913-915, 2014-03-25

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360002219105518208
• NII Article ID: 130004868205
• DOI: 10.1246/cl.140161
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/43/6/913/55641585/cl.140161.pdf
• Data Source:
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  • CiNii Articles
  • KAKEN