Fluorescent Dimer and Fiber of <i>meso</i>-Tetrakis{<i>o</i>-(isonicotinoylamino)phenyl}porphyrin Connected by Pd(II) Coordinations

• Sakiko Kasuya

  Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University

• Yukika Yamazawa

  Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University

• Natsuhiko Sugimura

  Materials Characterization Central Laboratory, Waseda University

• Toshimichi Shibue

  Materials Characterization Central Laboratory, Waseda University

• Teruyuki Komatsu

  Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University

抄録

A pair of meso-tetrakis{α,α,α,α-o-(isonicotinoylamino)phenyl}porphyrins (P1) was coupled by quadruple Pd(II) coordinations, generating a cofacial and fluorescent porphyrin dimer. Photoinduced electron transfers from the dimer to benzoquinones were investigated. Furthermore, Pd(II) coordinations to the α,β,α,β-atropisomer P2 yielded fluorescent porphyrin fiber with a monomolecular width.

収録刊行物

• Chemistry Letters

  Chemistry Letters 43 (7), 1008-1010, 2014-04-15

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644035660032
• NII論文ID: 130004868254
• DOI: 10.1246/cl.140243
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/43/7/1008/55641457/cl.140243.pdf
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