The significance of phosphate source in the preparation of functional luminescent phosphate materials

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  • KIM Minsung
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
  • KOBAYASHI Makoto
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
  • KATO Hideki
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
  • KAKIHANA Masato
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University

Abstract

The stability and reactivity of phosphate raw materials, including two water-soluble phosphates, ethylene glycol-conjugated phosphate (EG-P), and polyethylene glycol-conjugated phosphate (PEG-P) developed by our group, were examined with the aim of synthesizing phosphates with high functionalities. EG-P was found to gradually hydrolyze in an aqueous solution, resulting in the formation of H3PO4, while PEG-P was stable for more than two months. EG-P and PEG-P did not form insoluble materials in aqueous solution in the presence of many other cations, while precipitates were often observed using conventional phosphate raw materials. In particular, there were no precipitates in an aqueous solution of PEG-P in the presence of Ca2+ and Li+ ions, which easily formed insoluble phosphates in a given aqueous condition. Consequently, single-phase LiCaPO4 with high luminescence properties could be obtained by a polymerizable complex method employing PEG-P, while impurity phases were formed using other P sources, and KSrPO4 was formed as a single phase using EG-P and PEG-P.

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