Synthesis and Crystal Structure of Bis{2-[(2-hydroxymethylphenyl)-iminomethyl]phenolato}chromium(III) nitrate monohydrate

• KOIKAWA Masayuki

  Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University

• TOYOFUKU Takashi

  Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University

• MUTO Masahiro

  Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University

• YAMADA Yasunori

  Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University

• TOKII Tadashi

  Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University

抄録

The title compound, [Cr^III(HL1-H)₂]NO₃·H₂O, [H₂L1-H = 2-[2-(hydroxymethylphenyl)iminomethyl)phenol], was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the triclinic system, space group P1 and Z = 2 with cell parameters a = 9.409(5)Å, b = 12.330(5)Å, c = 13.789(5)Å, α = 116.13(3)°, β = 96.99(4)°, γ = 104.81(4)°, V = 1337.1(11)ų. The tridentate ligands bind to the chromium atom as monoanionic chelates.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 28 (0), 33-34, 2012

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390001205299322368
• NII論文ID: 130004953628
• DOI: 10.2116/xraystruct.28.33
• COI: 1:CAS:528:DC%2BC38XmtFGhs7k%3D
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/28/0/28_0_33/_pdf
• 本文言語コード: en
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