塩素処理によるトリクロラミン生成能と一般水質項目との関係

  • 中村 怜奈
    国立保健医療科学院生活環境研究部水管理研究分野 横浜市水道局
  • 小橋川 直哉
    国立保健医療科学院生活環境研究部水管理研究分野 厚生労働省健康局水道課
  • 小坂 浩司
    国立保健医療科学院生活環境研究部水管理研究分野
  • 久本 祐資
    京都大学大学院工学研究科
  • 越後 信哉
    京都大学大学院地球環境学堂
  • 浅見 真理
    国立保健医療科学院生活環境研究部水管理研究分野
  • 秋葉 道宏
    国立保健医療科学院

書誌事項

タイトル別名
  • Relashionship between trichloramine formation potential by chlorination and water quality parameters
  • エンソ ショリ ニ ヨル トリクロラミン セイセイノウ ト イッパン スイシツ コウモク ト ノ カンケイ

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抄録

 Formation potentials of trichloramine (NCl3), one of the major chlorinous odor compounds, in 15 raw waters were evaluated. Effects of co-existing compounds on NCl3 formation by chlorination were also examined. NCl3 formation potentials in 15 raw waters were 6-140 μg Cl2/L. The NCl3 formation potentials were correlated with ammonia concentration in raw water. NCl3 formation potentials in ammonium solution were higher than those in raw waters when ammonia concentrations in the sample solutions were same. NCl3 formation potentials of ammonium and glycine solutions decreased in the presence of natural organic matter (NOM). Thus, it was found that NOM reduced NCl3 formation in chlorination. Among 5 NOMs used, the effects of the Pony Lake fulvic acid (PLFA) on NCl3 formation was smaller than those of other 4 NOMs. This was because PLFA had the portions of the NCl3 precursors by chlorination. NCl3 formation potentials of ammonium and glycine solutions decreased in the presence of bromide ion. However, for ammonium solution, the effects of bromide ion was not observed when NOM was also co-exsited. In case of glycine solution, the effects of 20 and 50 μg/L of bromide ion was not observed, but those of 200 μg/L of bromide ion was observed when NOM was also co-exsited. The effects of bromide ion was not observed when bromide ion was added to raw waters.

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