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- Suzuki Daisuke
- Department of Materials Engineering, Graduate School of Engineering, The University of Tokyo
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- Yoshida Ryo
- Department of Materials Engineering, Graduate School of Engineering, The University of Tokyo PRESTO, Japan Science and Technology Agency
抄録
Different from simple stimuli-sensitive microgels, herein, we report “self-oscillating” microgel. This microgel shows an autonomic and periodical swelling/deswelling oscillation that is synchronized with redox oscillation of the Belousov-Zhabotinsky (BZ) reaction. The cross-linked microgels were synthesized by the copolymerization of N-isopropylacrylamide (NIPAm) with ruthenium tris(2,2′-bipyridine) [Ru(bpy)3] as a catalyst for the BZ reaction by surfactant-free aqueous precipitation polymerization. The self-oscillation of the microgels was detected by changes in optical transmittance. The microgels showed not only the swelling/deswelling oscillation, which is synchronized with the redox oscillation of the Ru(bpy)3 complex immobilized in the microgels, but also flocculating/dispersing oscillation around the phase transition temperature of the microgels, with a remarkable change in optical transmittance.
収録刊行物
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- Transactions of the Materials Research Society of Japan
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Transactions of the Materials Research Society of Japan 34 (3), 465-467, 2009
一般社団法人 日本MRS
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390001205513745152
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- NII論文ID
- 130005004022
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- COI
- 1:CAS:528:DC%2BD1MXhsFKktb7K
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- ISSN
- 21881650
- 13823469
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可