Formation Mechanism and Functionality of Multi-particle Layers of Aromatic Polyamides
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- Chiba Satoshi
- Graduate School of Science and Engineering, Yamagata University
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- Abe Yoko
- Department of Chemistry and Bioengineering, Graduate School of Science and Engineering, Iwate University
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- Shibasaki Yuji
- Department of Chemistry and Bioengineering, Graduate School of Science and Engineering, Iwate University
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- Fujimori Atsuhiro
- Graduate School of Science and Engineering, Yamagata University
抄録
We constructed two-dimensional integrated single particle layer on the water surface of aromatic polyamides (poly-(N-alkylated benzamides) abbrev. PABAn n: carbon number of side-chains) having both a rigid main-chain and a flexible side-chain with different lengths. Further, the build-up particle layers with highly regular arrangement along the c-axis are formed by Langmuir-Blodgett (LB) method. Molecular orientation and surface morphology of organized particle films of PABAn were investigated by performing surface pressure-area (π-A) isotherm, in-plane and out-of plane X-ray diffraction (XRD), and atomic force microscopy (AFM) measurements. These single particle layers of several aromatic polyamides on the water surface were highly condensed at 15 ℃. Results of out-of plane XRD measurement of multi-particle layers showed that the PABA, particle layers showed large periodicities of 50-60 Å at 15 ℃. From these experimental findings, it was concluded that the polymer synthesis method employed in the present study can be directly used to control their surface morphologies, behavior of two-dimensional integration and multi-particle layer formation.
収録刊行物
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- Transactions of the Materials Research Society of Japan
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Transactions of the Materials Research Society of Japan 36 (2), 145-148, 2011
一般社団法人 日本MRS
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詳細情報 詳細情報について
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- CRID
- 1390282680490239104
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- NII論文ID
- 130005004114
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- COI
- 1:CAS:528:DC%2BC3MXpvVelsrg%3D
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- ISSN
- 21881650
- 13823469
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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- 抄録ライセンスフラグ
- 使用不可