Dependency of the "Shape" on Surface Morphology of Organized Molecular Films of Cyclic and Linear Block Copolymer of Polyethylene Oxide – Butyl Acrylate
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- Hashimoto Masamichi
- Graduate School of Science and Engineering, Saitama University
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- Meng Qi
- Department of Functional Materials Science, Saitama University
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- Honda Satoshi
- Faculty of Engineering, Tokyo University of Science
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- Tezuka Yasuyuki
- Graduate School of Science and Engineering, Tokyo Institute of Technology
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- Yamamoto Takuya
- Graduate School of Science and Engineering, Tokyo Institute of Technology
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- Fujimori Atsuhiro
- Graduate School of Science and Engineering, Saitama University
抄録
A "topological polymer chemistry" at air/water interface is investigated by using an amphiphilic linear and cyclic block copolymers. A cyclic copolymer and two kind of linear polymers (AB-type diblock and ABA-type triblock copolymers) with same components were used in the study. The relatively stable monolayers of these three kinds of copolymers were formed at the air/water interface. The analogous condensed tendency and temperature dependency were observed in surface pressure-area isotherms of three kinds of monolayers. It is considered that molecular orientation at air/water interface of two kinds of liner block copolymers is similar to that of cyclic block copolymer. From the result of atomic force microscopic observation of transfered films, monolayers of the three kinds of polymers have formed a very similar morphology at mesoscopic scale under the conditions at room temperature and the constant compression speed. It finds that ABA type triblock liner copolymer formed fiber-like surface morphology by the two-dimensional crystallization based on the low compression speed. On the other hand, cyclic block copolymer formed shapeless domain.
収録刊行物
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- Transactions of the Materials Research Society of Japan
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Transactions of the Materials Research Society of Japan 39 (1), 83-86, 2014
一般社団法人 日本MRS
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詳細情報 詳細情報について
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- CRID
- 1390001205511920128
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- NII論文ID
- 130005004299
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- ISSN
- 21881650
- 13823469
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可