Radical Addition to Corannulene Mediated by Visible-light-photoredox Catalysts

  • Kazunari Nakajima
    Institute of Engineering Innovation, School of Engineering, The University of Tokyo
  • Yuya Ashida
    Institute of Engineering Innovation, School of Engineering, The University of Tokyo
  • Sunao Nojima
    Institute of Engineering Innovation, School of Engineering, The University of Tokyo
  • Yoshiaki Nishibayashi
    Institute of Engineering Innovation, School of Engineering, The University of Tokyo

Abstract

<jats:title>Abstract</jats:title> <jats:p>Functionalization of corannulene has been extensively studied, however, radical addition reactions toward corannulene have been unexplored to date. Herein, we report the photochemical addition reaction of amines to corannulene via radical intermediates using photoredox catalysts.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 44 (4), 545-547, 2015-01-17

    Oxford University Press (OUP)

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