Maltopentaose-conjugated Thermoresponsive Block Copolymer: Precision Synthesis through RAFT Polymerization of <i>N</i>,<i>N</i>-Diethylacrylamide

• Togashi Daichi

  Department of Polymer Science and Engineering, Graduate School of Science and Engineering, Yamagata University

• Otsuka Issei

  Université Grenoble Alpes, CERMAV CNRS, CERMAV

• Borsali Redouane

  Université Grenoble Alpes, CERMAV CNRS, CERMAV

• Kawaguchi Seigou

  Department of Polymer Science and Engineering, Graduate School of Science and Engineering, Yamagata University

• Narumi Atsushi

  Department of Polymer Science and Engineering, Graduate School of Science and Engineering, Yamagata University

抄録

A strategy to directly prepare maltopentaose-block-poly(N,N-diethylacrylamide), Mal₅-block-PDEAA, based on the reversible addition–fragmentation chain-transfer (RAFT) polymerization technique as a metal-free process is described. Mal₅-block-PDEAA generated stable nanoaggregates in water with an average hydrodynamic radius (R_h) of 109 nm by heating to around the human body temperature; thus, the present strategy is useful for the preparation of polymers for biomedical applications.

収録刊行物

• Chemistry Letters

  Chemistry Letters 44 (4), 428-430, 2015

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204588179328
• NII論文ID: 130005062147
• DOI: 10.1246/cl.141106
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/44/4/428/55642878/cl.141106.pdf
• 本文言語コード: en
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