Synthesis and Photophysical Properties of Extended π-Conjugative and Push-Pull-Type 1,4-Diaryl-1-thio-1,3-butadienes Incorporated in a Dibenzobarrelene Skeleton

• Tatsuro Annaka

• Norio Nakata

• Akihiko Ishii

抄録

1,4-Bis(p-ethynylphenyl)-1-thio-1,3-butadiene derivatives incorporated in a dibenzobarrelene skeleton were yielded by Sonogashira reactions of the corresponding 1,4-bis(p-halophenyl) derivatives, and push–pull-type sulfoxide and sulfone derivatives were obtained by oxidation of the amino derivative prepared by Buchwald–Hartwig reaction of the 1,4-bis(p-halophenyl) derivatives. These compounds show red-shifted yellow and orange fluorescence [λem(CH2Cl2) = 522–562 nm, λem(solid) = 522–580 nm] in comparing with the unsubstituted, 1,4-diphenyl-1-thio-1,3-butadiene derivative [λem(CH2Cl2) = 491 nm, λem(solid) = 483 nm].

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 88 (4), 554-561, 2015-04

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1524232504427425664
• NII論文ID: 130005064981
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.20140351
• NDL書誌ID: 026322151
• Web Site: http://id.ndl.go.jp/bib/026322151
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I026322151
• Web Site: https://academic.oup.com/bcsj/article-pdf/88/4/554/56277799/bcsj.20140351.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
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  • Crossref
  • CiNii Articles
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