Asymmetric Autocatalysis Triggered by Chiral Crystal of Achiral Ethylenediamine Sulfate

• Arimasa Matsumoto

  Department of Applied Chemistry, Tokyo University of Science

• Takahiro Ide

  Department of Applied Chemistry, Tokyo University of Science

• Yoshiyasu Kaimori

  Department of Applied Chemistry, Tokyo University of Science

• Satoshi Fujiwara

  Department of Applied Chemistry, Tokyo University of Science

• Kenso Soai

  Department of Applied Chemistry, Tokyo University of Science

Abstract

Achiral ethylenediamine forms chiral structures spontaneously when crystallized as the sulfate salt. By using these chiral crystals of ethylenediamine sulfate (ethylenediammonium sulfate), asymmetric autocatalysis of pyrimidyl alkanol affords a highly enantioenriched product with chirality that is determined by the chirality of the crystals.

Journal

• Chemistry Letters

  Chemistry Letters 44 (5), 688-690, 2015-02-14

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360283694082364032
• NII Article ID: 130005067965
• DOI: 10.1246/cl.150052
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/44/5/688/55644706/cl.150052.pdf
• Data Source:
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  • CiNii Articles
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