Charge-transfer Complex Formed with Bowl-shaped Corannulene as Electron Donor and Planar 7,7,8,8-Tetracyanoquinodimethane as Electron Acceptor
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- Yukihiro Yoshida
- Faculty of Agriculture, Meijo University
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- Kazuhide Isomura
- Department of Applied Physics, Nagoya University
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- Yuto Nakamura
- Department of Applied Physics, Nagoya University
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- Hideo Kishida
- Department of Applied Physics, Nagoya University
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- Gunzi Saito
- Faculty of Agriculture, Meijo University
抄録
<jats:title>Abstract</jats:title> <jats:p>Vacuum cosublimation gave the first charge-transfer (CT) solid of π-bowl corannulene as an electron donor with π-planar 7,7,8,8-tetracyanoquinodimethane (TCNQ) as an electron acceptor, which consists of segregated and alternating columns. In the latter column, hub carbons with significant HOMO coefficients form π–π interactions with adjacent TCNQ only on the convex side of the corannulene, resulting in the difference in the CT interaction between the two sides.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 44 (5), 709-711, 2015-02-28
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360283694082370048
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- NII論文ID
- 130005067982
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- ISSN
- 13480715
- 03667022
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