Charge-transfer Complex Formed with Bowl-shaped Corannulene as Electron Donor and Planar 7,7,8,8-Tetracyanoquinodimethane as Electron Acceptor

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Vacuum cosublimation gave the first charge-transfer (CT) solid of π-bowl corannulene as an electron donor with π-planar 7,7,8,8-tetracyanoquinodimethane (TCNQ) as an electron acceptor, which consists of segregated and alternating columns. In the latter column, hub carbons with significant HOMO coefficients form π–π interactions with adjacent TCNQ only on the convex side of the corannulene, resulting in the difference in the CT interaction between the two sides.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 44(5), 709-711, 2015

    公益社団法人 日本化学会

各種コード

  • NII論文ID(NAID)
    130005067982
  • 本文言語コード
    ENG
  • ISSN
    0366-7022
  • データ提供元
    J-STAGE 
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