Aromatic C–H Borylation by Nickel Catalysis

• Hua Zhang

  Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Science, Nagoya University

• Shinya Hagihara

  Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Science, Nagoya University

• Kenichiro Itami

  Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Science, Nagoya University

抄録

The first nickel-catalyzed aromatic C–H borylation is described. In the presence of catalytic amounts of [Ni(cod)2], tricyclopentylphosphine, and CsF, benzene and indole derivatives can be borylated with B2pin2. The N-heterocyclic carbene IPr was also found to be an effective ligand. Kinetic isotope effect experiments showed that C–H cleavage is likely involved in the rate-determining step.

収録刊行物

• Chemistry Letters

  Chemistry Letters 44 (6), 779-781, 2015-03-14

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360565169059088384
• NII論文ID: 130005074587
• DOI: 10.1246/cl.150154
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/44/6/779/55638908/cl.150154.pdf
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