Reaction Integration Using Electrogenerated Cationic Intermediates

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  • Yoshida Jun-ichi
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Shimizu Akihiro
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Ashikari Yosuke
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Morofuji Tatsuya
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Hayashi Ryutaro
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Nokami Toshiki
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Nagaki Aiichiro
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

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  • Award Accounts : The Chemical Society of Japan Award for 2012 : Reaction Integration Using Electrogenerated Cationic Intermediates

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Abstract

Reaction integration which combines multiple reactions in a single operation in one pot or in a flow system without isolating intermediates enhances the power and speed of organic synthesis to meet future demands for synthesis of various organic molecules. This article provides a brief outline of a new field of organic synthesis based on time integration and space integration of reactions using unstable reactive cationic intermediates generated by electrochemical oxidation.

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