Unusual <i>O</i>-Alkylation of 2-Hydroxy-1,4-naphthoquinone Utilizing Alkoxymethyl Chlorides

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  • Ogata Tokutaro
    School of Pharmacy and Pharmaceutical Sciences, Mukogawa Women’s University
  • Yoshida Tomoyo
    School of Pharmacy and Pharmaceutical Sciences, Mukogawa Women’s University
  • Tanaka Manami
    School of Pharmacy and Pharmaceutical Sciences, Mukogawa Women’s University
  • Fukuhara Chie
    School of Pharmacy and Pharmaceutical Sciences, Mukogawa Women’s University
  • Shimizu Maki
    School of Pharmacy and Pharmaceutical Sciences, Mukogawa Women’s University
  • Ishii Junko
    School of Pharmacy and Pharmaceutical Sciences, Mukogawa Women’s University
  • Nishiuchi Arisa
    School of Pharmacy and Pharmaceutical Sciences, Mukogawa Women’s University
  • Inamoto Kiyofumi
    School of Pharmacy and Pharmaceutical Sciences, Mukogawa Women’s University
  • Kimachi Tetsutaro
    School of Pharmacy and Pharmaceutical Sciences, Mukogawa Women’s University

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  • Communication to the Editor : Unusual O-Alkylation of 2-Hydroxy-1,4-naphthoquinone Utilizing Alkoxymethyl Chlorides

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Abstract

A new type of O-alkylation of 2-hydroxy-1,4-naphthoquinone with alkoxymethyl chlorides is described. The reaction course can be controlled by the choice of base and yields O-alkylated or O-alkoxymethylated products in high yield with high selectivity.

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