Unusual Tautomeric Energetics in 4n Azaheterocycles

• Hatanaka Masashi

  School of Engineering, Tokyo Denki University

書誌事項

タイトル別名

• Unusual Tautomeric Energetics in 4<i>n</i> Azaheterocycles

抄録

Unusual imino preference in 4n azaheterocycles is theoretically analyzed. It is attributed to less topological charge stability of the amino forms due to antisymmetric nonbonding molecular orbitals. The theory is applicable for designing stable imino species. The same analysis is also applicable for hydroxyl/oxo tautomerism, and results in very stable lactams.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 88 (8), 1147-1149, 2015

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204141103616
• NII論文ID: 130005092052
• NII書誌ID: AA00580132
• DOI: 10.1246/bcsj.20150105
• ISSN: 13480634
• ISSN: 00092673
• NDL書誌ID: 026648309
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I026648309
• Web Site: https://academic.oup.com/bcsj/article-pdf/88/8/1147/56278175/bcsj.20150105.pdf
• 本文言語コード: en
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