Straightforward Synthesis of HOMSi Reagents via sp2 C–H Silylation

• Yasunori Minami

  Research and Development Initiative, Chuo University

• Takeshi Komiyama

  Department of Applied Chemistry, Chuo University

• Tamejiro Hiyama

  Research and Development Initiative, Chuo University

Abstract

Straightforward C–H silylation of heteroarenes and alkenes was found to provide efficient access to organo-HOMSi reagents as stable silicon reagents for cross-coupling. Various heteroarenes and terminal alkenes were silylated to show the versatility of the reaction. This method was applied in double silylation reactions to give bisHOMSi reagents. The silylation products could be used in the cross-coupling reaction with haloarenes easily.

Journal

• Chemistry Letters

  Chemistry Letters 44 (8), 1065-1067, 2015-05-19

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360565169059110400
• NII Article ID: 130005092594
• DOI: 10.1246/cl.150359
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/44/8/1065/55644523/cl.150359.pdf
• Data Source:
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  • CiNii Articles
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