Evaluation of the Tensile Strength of Electron Beam Irradiated Powdered Ultra High Molecular Weight-Polyethylene (UHMWPE) Prior to Sintering

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We have studied the variation in tensile strength (σb), fracture strain (εf) and Young modulus (dσ/dε) of low voltage electron beam irradiation (HLEBI) on powdered ultra-high molecular weight-polyethylene from 0.043 to 0.43 MGy prior to sintering. The low dose of 0.043 MGy-HLEBI enhanced the σb, εf and dσ/dε, as well as increased the crystallinity ratio from 37 to 46% evaluated by differential scanning calorimetry (DSC). An additional dose apparently decreased the σb and εf, as well as the melting point from approximately 412 to 406 K and the crystallinity ratio from 46 to 43% for 0.043 to 0.43 MGy, respectively. Irradiation induces two competitive mechanisms, namely (i) the scission of chains and (ii) the crosslinking of chains. The discussion is focused on these mechanisms.

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