Reductive Transformation of CO2 with Hydrosilanes Catalyzed by Simple Fluoride and Carbonate Salts
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- Ken Motokura
- Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology
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- Masaki Naijo
- Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology
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- Sho Yamaguchi
- Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology
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- Akimitsu Miyaji
- Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology
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- Toshihide Baba
- Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology
抄録
<jats:title>Abstract</jats:title> <jats:p>Hydrosilylation of CO2 catalyzed by simple fluoride and carbonate salts, such as CsF and K2CO3, is described. Total yields up to 87% for the formylated product were achieved. Mechanistic investigations indicate the reaction proceeds via the formation of an active formate species. This catalytic system was also found to be applicable to formamide synthesis from amines, CO2, and hydrosilane.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 44 (9), 1217-1219, 2015-06-19
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360846644035835648
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- NII論文ID
- 130005096884
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- ISSN
- 13480715
- 03667022
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