<i>Pseudo</i>-<i>S</i>₆ Complex Cations of a Hexakis-<i>N</i>-methylformamide Nickel(II) Complex

• SAKIYAMA Hiroshi

  Department of Material and Biological Chemistry,Faculty of Science, Yamagata University

• MITSUHASHI Ryoji

  Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University

• MIKURIYA Masahiro

  Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University

Abstract

The nickel(II) complex [Ni(NMF)₆](BPh₄)₂ [NMF = N-methylformamide] [hexakis(N-methylformamide-κO)nickel(II) bis(tetraphenylborate)] was prepared, and characterized by a single-crystal X-ray method. The compound crystallizes in the triclinic space group P1 and Z = 2 with the following cell parameters: a = 10.680(2)Å, b = 13.271(3)Å, c = 19.960(4)Å, α = 86.043(6)°, β = 84.483(6)°, γ = 87.335(7)°, V = 2807.0(10)ų. Two types of [Ni(NMF)₆]²⁺ cations are found in a crystal, but both have a pseudo-S₆ symmetry.

Journal

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 31 (0), 45-46, 2015

  The Japan Society for Analytical Chemistry

Keywords

• Materials Chemistry
• Analytical Chemistry

Details

• CRID: 1390282680277226368
• NII Article ID: 130005100102
• DOI: 10.2116/xraystruct.31.45
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/31/0/31_45/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed