Effect of Water Added into Acetonitrile Solvent on Oxidation of Benzene with Hydrogen Peroxide over Iron Complexes Encapsulated in Zeolite

• Syuhei Yamaguchi

  Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University

• Tetsuya Ohnishi

  Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University

• Yuki Miyake

  Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University

• Hidenori Yahiro

  Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University

抄録

Catalytic activity of iron complex-encapsulated zeolite catalyst ([Fe(bpy)3]2+@Y) for oxidation of benzene increased with increasing the amount of water added to acetonitrile. Maximum value of catalytic activity was obtained when the volume ratio of the solvents was equal (CH3CN:H2O = 1:1). After reaction at 24 h, the turnover number of [Fe(bpy)3]2+@Y was higher than that of [Fe(bpy)3](ClO4)2 as a homogeneous catalyst.

収録刊行物

• Chemistry Letters

  Chemistry Letters 44 (10), 1287-1288, 2015-06-20

  Oxford University Press (OUP)

詳細情報

• CRID: 1360283694082411392
• NII論文ID: 130005101462
• DOI: 10.1246/cl.150479
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/44/10/1287/55639122/cl.150479.pdf
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