Synthesis and Characterization of Poly(arylene vinylene ketone)s Bearing 1,1′-Binaphthylene Units through Mizoroki–Heck Coupling Polymerization

• Tsukamoto Tadashi

  Department of Polymer Science and Engineering, Graduate School of Science and Engineering, Yamagata University

• Maeyama Katsuya

  Department of Polymer Science and Engineering, Graduate School of Science and Engineering, Yamagata University

• Higashibayashi Shuhei

  Research Center for Integrative Molecular Systems, Institute for Molecular Science

• Sakurai Hidehiro

  Division of Applied Chemistry, Graduate School of Engineering, Osaka University

Abstract

Mizoroki–Heck coupling polymerization of diiodonated 1,1′-binaphthyls ((S)-1/2) with divinylbenzenes (DVB-H/-Me/-OMe) afforded a series of poly(arylene vinylene ketone)s (PAVK1–PAVK6). The resulting PAVKs have high thermal stabilities, excellent solubilities in organic solvents, and pale blue to green fluorescence properties.

Journal

• Chemistry Letters

  Chemistry Letters 44 (12), 1780-1782, 2015

  The Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1390001204589238016
• NII Article ID: 130005112558
• DOI: 10.1246/cl.150833
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/44/12/1780/55642958/cl.150833.pdf
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed