Synthesis of (Y,Er)₂O₃ Films from Multiple-Nuclei EDTA・(Y,Er)・H Complexes by Flame Spray Method
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- Komatsu Keiji
- Department of Materials Science and Technology, Nagaoka University of Technology
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- Sekiya Tetsuo
- Department of Materials Science and Technology, Nagaoka University of Technology
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- Toyama Ayumu
- Department of Materials Science and Technology, Nagaoka University of Technology
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- Shirai Tomoyuki
- Department of Materials Science and Technology, Nagaoka University of Technology
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- Nakamura Atsushi
- Department of Materials Science and Technology, Nagaoka University of Technology Chubu Chelest
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- Ohshio Shigeo
- Department of Materials Science and Technology, Nagaoka University of Technology
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- Toda Ikumi
- Department of Materials Science and Technology, Nagaoka University of Technology
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- Muramatsu Hiroyuki
- Department of Materials Science and Technology, Nagaoka University of Technology
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- Saitoh Hidetoshi
- Department of Materials Science and Technology, Nagaoka University of Technology
書誌事項
- タイトル別名
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- Synthesis of (Y,Er)<sub>2</sub>O<sub>3</sub> Films from Multiple-Nuclei EDTA·(Y,Er)·H Complexes by Flame Spray Method
- Synthesis of (Y,Er)<sub>2</sub>O<sub>3</sub> Films from Multiple-Nuclei EDTA·(Y,Er)·H Complexes by Flame Spray Method
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抄録
In this investigation, rare earth metal oxide films were synthesized from metal complexes of ethylenediaminetetraacetic acid (metal-EDTA) by utilizing a flame spray technique. Two raw metal-EDTA powders were prepared as starting materials in order to synthesize (Y,Er)2O3 films on stainless steel (SUS) substrates by a reaction that is promoted by the combustion of gaseous H2-O2. Molecularly mixed EDTA·(Y,Er)·H and mechanically mixed EDTA·Y·H + EDTA·Er·H complexes were subsequently prepared. The existence of Y2O3 and Er2O3 crystalline phases was confirmed for the EDTA·Y·H + EDTA·Er·H mixtures. Lamellar structures were formed on the film with a porosity of 9.5%. Alternatively, a homogenous, (Y,Er)2O3 film was obtained from the EDTA·(Y,Er)·H complex, with a film porosity of 31.8%. These results indicate that uniform (Y,Er)2O3 films were synthesized on SUS substrates from molecularly mixed EDTA·(Y,Er)·H powders.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 57 (1), 70-74, 2016
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390282679231352192
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- NII論文ID
- 130005115846
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- NII書誌ID
- AA1151294X
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 027010387
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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