A Water-soluble Ni Dihydrido Complex That Reduces O<sub>2</sub> to H<sub>2</sub>O in Water

DOI Web Site 参考文献28件
  • Takashita Keisuke
    Center for Small Molecule Energy, Kyushu University Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Matsumoto Takahiro
    Center for Small Molecule Energy, Kyushu University Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University
  • Yatabe Takeshi
    Center for Small Molecule Energy, Kyushu University Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University
  • Nakai Hidetaka
    Center for Small Molecule Energy, Kyushu University Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University
  • Suzuki Masatatsu
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Ogo Seiji
    Center for Small Molecule Energy, Kyushu University Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University

抄録

We report the first example of reduction of O2 to H2O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O2 by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1H NMR, ESR, and UV–vis spectroscopies.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 45 (1), 72-74, 2016

    公益社団法人 日本化学会

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