Autonomously Substitutable Organosilane Thin Films Based on Dynamic Covalent Diarylbibenzofuranone Units

Access this Article

Author(s)

    • Sato Tomoya
    • Graduate School of Engineering, Kyushu University|Department of Organic and Polymeric Materials, Tokyo Institute of Technology
    • Imato Keiichi
    • Graduate School of Engineering, Kyushu University|Department of Organic and Polymeric Materials, Tokyo Institute of Technology
    • Kosuge Takahiro
    • Department of Organic and Polymeric Materials, Tokyo Institute of Technology
    • Ohishi Tomoyuki
    • Department of Organic and Polymeric Materials, Tokyo Institute of Technology|Institute for Materials Chemistry and Engineering, Kyushu University
    • Higaki Yuji
    • Graduate School of Engineering, Kyushu University|Institute for Materials Chemistry and Engineering, Kyushu University
    • Takahara Atsushi
    • Graduate School of Engineering, Kyushu University|Institute for Materials Chemistry and Engineering, Kyushu University
    • Otsuka Hideyuki
    • Graduate School of Engineering, Kyushu University|Department of Organic and Polymeric Materials, Tokyo Institute of Technology|Institute for Materials Chemistry and Engineering, Kyushu University

Abstract

Autonomously substitutable organosilane thin films based on diarylbibenzofuranone (DABBF) units were prepared, and the radical exchange reactions of the DABBF units at the surface resulted in chemically reversible surface character changes without external stimuli. The reversible changes of the surface properties were confirmed by X-ray photoelectron spectroscopy and water contact angle measurements.

Journal

  • Chemistry Letters

    Chemistry Letters 45(1), 36-38, 2016

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130005118770
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
Page Top