Ferrocenyl-substituted Bicyclo[1.1.1]pentasilanes: Evaluation of Significant Interactions between Ferrocenyl Units and Rigid Silicon Cages

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Author(s)

    • Ishida Shintaro
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • Iwamoto Takeaki
    • Department of Chemistry, Graduate School of Science, Tohoku University

Abstract

Ferrocenyl-substituted bicyclo[1.1.1]pentasilanes <b>1</b>, <b>2</b>, and <b>3</b> were synthesized by the reactions of bromo-substituted bicyclo[1.1.1]pentasilanes with lithioferrocene. Significant interactions between bicyclo[1.1.1]pentasilane and ferrocenyl units were suggested by cyclic voltammetry, UV–vis absorption spectrum, and theoretical calculations.

Journal

  • Chemistry Letters

    Chemistry Letters 45(2), 235-237, 2016

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130005124719
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
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