Computational Picture of Silyl Transfer from Silylsilatranes to Arylpalladium Chloride

• Jing-Dong Guo

• Takahiro Sasamori

• Yutaro Yamamoto

Abstract

The previously reported palladium-catalyzed silylation of aryl chlorides with silylsilatranes was theoretically reinvestigated by DFT calculations with a focus on the effect of the transannular Si–N coordination on silyl transfer. The Si–N coordination proved to be not so influential as to accelerate the silyl transfer. However, it should be of benefit to use silylsilatranes as silylating agents because of their easy handling and facile preparation.

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 89 (2), 192-194, 2016-02

  Tokyo : Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1521699229656978688
• NII Article ID: 130005125597
• NII Book ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.20150343
• NDL BIB ID: 027102644
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I027102644
• Web Site: https://academic.oup.com/bcsj/article-pdf/89/2/192/56278716/bcsj.20150343.pdf
• Text Lang: en
• NDL Source Classification:
  • ZP1(科学技術--化学・化学工業)
• Data Source:
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN