Effects of Chemical Compositions on Electrical Properties of Low Temperature Co-fired Alumina Ceramics with Built-in Silver Electrodes

  • Shigeno Koichi
    National Institute of Technology, Ube College Graduate School of Science and Engineering, Yamaguchi University
  • Asakawa Tadashi
    National Institute of Technology, Ube College
  • Kuraoka Yuto
    National Institute of Technology, Ube College
  • Fujimori Hirotaka
    Graduate School of Science and Engineering, Yamaguchi University

Abstract

Recent studies by the authors have been intended to develop sintering additives that can make alumina sintered at low temperature with a small quantity. In the case of use of CuO-TiO2-Nb2O5-Ag2O type additives, high-density alumina was obtained by firing at a temperature of 900℃ or below, even though additives content was only 5mass%. In this study, co-firing of above materials with Ag-electrodes at 900℃ or below was examined in order to clarify the relationship between chemical compositions and their reactivity. The results showed that reactivity was highly affected by the Ag2O content in the sintering additives. When the content of Ag2O was higher, any disappearance of Ag-electrodes was not found and electric properties were almost the same as those of conventional LTCC materials. Finally, these results indicated the obtained materials had possibility to be applied to LTCC modules having high thermal conductivity.

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