Surface Micro-XAFS and Its Application to Real-time Observation of Organic Thin Films

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Abstract

X-ray absorption fine structure (XAFS) is a powerful tool to investigate electronic structures, valence states and molecular orientations at solid surfaces. In order to observe nano-scaled dynamic phenomena at solid surfaces, we have developed a micro-XAFS system using a photoelectron emission microscopy (PEEM) excited by synchrotron radiation in soft X-ray region. Here we explain the performance of our system concentrating on the recent development of quick measurements, and demonstrated that a PEEM image can be taken in a short time down to 10 msec. As an application of the system, we present the results for the real-time mapping of molecular orientations at nanometer scale for organic thin films. We demonstrated that the orientations of organic molecules in a microscopic region change during surface diffusion.

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