Reaction of 2a,8b-Dihydrobenzo[<i>b</i>]cyclobute[<i>d</i>]pyran-3-ones with Dimethylsulfoxonium Methylide
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- Tanaka Toru
- Kyoto Pharmaceutical University
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- Nagahama Masaki
- Kyoto Pharmaceutical University
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- Yadav Navnath Dnyanoba
- Kyoto Pharmaceutical University
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- Iwasaki Hiroki
- Kyoto Pharmaceutical University
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- Ozeki Minoru
- Kyoto Pharmaceutical University
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- Kojima Naoto
- Kyoto Pharmaceutical University
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- Yamashita Masayuki
- Kyoto Pharmaceutical University
Bibliographic Information
- Other Title
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- Reaction of 2a,8b-Dihydrobenzo[b]cyclobute[d]pyran-3-ones with Dimethylsulfoxonium Methylide
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Abstract
Using dimethylsulfoxonium methylide as the methylene transfer reagent, 2a,8b-dihydrobenzo[b]cyclobute[d]pyran-3-ones were converted into 2,2′-biphenol derivatives as major products and dihydrodibenzofurans as minor products. The reaction mechanism was extrapolated from a deuteration experiment with CD2=S(O)(CD3)2.
Journal
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- Chemical and Pharmaceutical Bulletin
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Chemical and Pharmaceutical Bulletin 64 (7), 1056-1061, 2016
The Pharmaceutical Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679155585408
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- NII Article ID
- 130005160051
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- NII Book ID
- AA00602100
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- ISSN
- 13475223
- 00092363
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- NDL BIB ID
- 027451953
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- PubMed
- 27373667
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed