Transition Metal-catalyzed Fixation of Carbon Dioxide <i>via</i> Carbon–carbon Bond Formation

• FUJIHARA Tetsuaki

  Dept. of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University

• TSUJI Yasushi

  Dept. of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University

Bibliographic Information

Other Title

• 遷移金属錯体触媒を用いた炭素–炭素結合形成を経る二酸化炭素固定化反応
• Transition Metal-catalyzed Fixation of Carbon Dioxide via Carbon-carbon Bond Formation

Abstract

Carbon dioxide (CO₂) is a readily available carbon source, but the thermodynamic characteristics of CO₂ limit its widespread use in chemical reactions. This review summarizes the transformation of CO₂ via carbon–carbon bond-forming reactions. Ni complexes catalyzed the carboxylation of less reactive aryl chlorides and double carboxylation of internal alkynes in the presence of suitable reducing agents such as Mn or Zn powders under 1 atm of CO₂. Using Cu complexes as catalysts under CO₂ atmosphere, hydrocarboxylation and silacarboxylation of alkynes proceeded efficiently using hydrosilanes and silylboranes, respectively, as the reagents.

Journal

• Journal of the Japan Petroleum Institute

  Journal of the Japan Petroleum Institute 59 (3), 84-92, 2016-05-01

  The Japan Petroleum Institute

Keywords

• Carbon dioxide
• Homogeneous catalysis
• Nickel catalyst
• Copper catalyst
• Carbon–carbon bond formation

Details

• CRID: 1390282680166890496
• NII Article ID: 130005161536
• NII Book ID: AA11590615
• DOI: 10.1627/jpi.59.84
• ISSN: 1349273X
• ISSN: 13468804
• NDL BIB ID: 027339296
• Web Site: http://id.ndl.go.jp/bib/027339296
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I027339296
• Web Site: https://www.jstage.jst.go.jp/article/jpi/59/3/59_84/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed