Preparation of Liquid-Crystalline Polymers Based on Natural Microfibril Materials

  • IWAMI Yuko
    Department of Applied Chemistry, Faculty of Engineering, Oita University
  • TOMITAKA Shiori
    Department of Applied Chemistry, Faculty of Engineering, Oita University
  • NATA Masanori
    Department of Applied Chemistry, Faculty of Engineering, Oita University
  • UJIIE Seiji
    Department of Applied Chemistry, Faculty of Engineering, Oita University

Bibliographic Information

Other Title
  • ヒドロキシプロピルセルロースへの置換基の導入による液晶材料化<br/>—熱的性質および配向挙動—
  • ヒドロキシプロピルセルロースへの置換基の導入による液晶材料化 : 熱的性質および配向挙動
  • ヒドロキシプロピルセルロース エ ノ チカンキ ノ ドウニュウ ニ ヨル エキショウ ザイリョウカ : ネツテキ セイシツ オヨビ ハイコウ キョドウ

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Abstract

Novel thermotropic liquid-crystalline cellulose derivatives were synthesized by the addition reaction of hydroxypropylcellulose with isocyanate. The liquid-crystalline cellulose derivatives exhibited columnar mesophases on heating and cooling. The cellulose derivatives formed a water-absorbing resin and their resinous gel films showed water-absorbency and stability with time. The resin plates of the cellulose derivatives were obtained by a hot press process at liquid-crystalline temperatures. They showed a tensile strength that was stronger than that of polypropylene.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 73 (4), 361-365, 2016

    The Society of Polymer Science, Japan

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