Palladium-catalyzed Asymmetric Allylic Alkylation Using <i>C</i>₂-symmetric Chiral Bidentate Bis(<i>N</i>-heterocyclic carbene) Ligands with the <i>o</i>-Xylylene Framework

• Yamaguchi Yoshitaka

  Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University

• Suzuki Yasutomo

  Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University

• Matsumoto Sawako

  Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University

• Anezaki Satoshi

  Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University

• Asami Masatoshi

  Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University

抄録

An asymmetric allylic alkylation reaction of 1,3-diphenylprop-2-en-1-yl acetate with dimethyl malonate was examined using C₂-symmetric chiral bidentate bis(N-heterocyclic carbene)-based palladium catalysts. The alkylated product was obtained in 96% yield with good enantioselectivity (80% ee).

収録刊行物

• Chemistry Letters

  Chemistry Letters 45 (7), 798-800, 2016

  公益社団法人 日本化学会

キーワード

• <i>N</i>-Heterocyclic carbene
• Palladium complex
• Asymmetric allylic alkylation

詳細情報

• CRID: 1390001204589154432
• NII論文ID: 130005252992
• DOI: 10.1246/cl.160235
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://www.journal.csj.jp/doi/pdf/10.1246/cl.160235
• 本文言語コード: en
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