Effect of Solvents on the Surface Modification of Hydrophilic Macro-Porous Particles with an Ion-Exchange Monomer Having Both Anion and Cation Exchange Groups

• SHIBATA Kanami

  Graduate School of Life and Environmental Science, Kyoto Prefectural University

• TANIGAWA Tetsuya

  Graduate School of Life and Environmental Science, Kyoto Prefectural University

• ITO Haruka

  Graduate School of Life and Environmental Science, Kyoto Prefectural University

• KUBO Takuya

  Graduate School of Engineering, Kyoto University

• HOSOYA Ken

  Graduate School of Life and Environmental Science, Kyoto Prefectural University

Abstract

An ion-exchange monomer including an anion exchange group and a cation exchange group, 2-methacryloyloxyethyl- phosphoryl choline (MPC) was introduced on the surface of uniformly sized, hydrophilic macro-porous polymer particle. We carefully studied several solvents utilized for the surface modification to elucidate solubility of the monomer as well as its polymer into each solvent. Based on the change in existing form of poly-MPC modified on the surface of stationary phases, ion-exchange properties of poly-MPC were controllable to result in interesting selectivity changes in HPLC.

Journal

• CHROMATOGRAPHY

  CHROMATOGRAPHY 37 (3), 99-104, 2016

  The Society for Chromatographic Sciences

Keywords

• Ion-exchange group
• Uniformly sized particle
• Surface modification
• MPC

Details

• CRID: 1390001205745100032
• NII Article ID: 130005277409
• NII Article ID: 40020987444
• NII Book ID: AA1137755X
• DOI: 10.15583/jpchrom.2016.004
• ISSN: 13483315
• ISSN: 13428284
• NDL BIB ID: 027713100
• Web Site: http://id.ndl.go.jp/bib/027713100
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I027713100
• Web Site: https://www.jstage.jst.go.jp/article/jpchrom/37/3/37_2016.004/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed