Selective HPLC Analysis of Polycylic Aromatic Hydrocarbons Using Exciplex Fluorescence Phenomenon
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- TODOROKI Kenichiro
- School of Pharmaceutical Sciences, University of Shizuoka
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- YANAGO Keiko
- Faculty of Pharmaceutical Sciences, Fukuoka University
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- YOSHIDA Hideyuki
- Faculty of Pharmaceutical Sciences, Fukuoka University
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- NOHTA Hitoshi
- Faculty of Pharmaceutical Sciences, Fukuoka University
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- YAMAGUCHI Masatoshi
- Faculty of Pharmaceutical Sciences, Fukuoka University
Bibliographic Information
- Other Title
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- エキサイプレックス蛍光現象を利用する多環芳香族炭化水素のHPLC分析
- エキサイプレックス ケイコウ ゲンショウ オ リヨウ スル タカン ホウコウゾク タンカスイソ ノ HPLC ブンセキ
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Abstract
We have developed a sensitive analytical method for polycyclic aromatic hydrocarbons (PAHs) using exciplex fluorescence phenomenon expressed between PAHs and aniline derivatives. From screening study, 8 kinds of pyrenes, anthracene, acridine and perylene proved to form exciplex fluorescence. As acceptor molecule for exciplex fluorescence formation, many aniline derivatives such as N,N-dimethylaniline and N,N-di-n-propylaniline could be applicable. Since exciplex fluorescence strongly expressed in low polar organic solvents, we proposed a simultaneous determination method for pyrenes combined with normal-phase HPLC. We successfully applied this method to quantification of urinary 1-hydroxypyrene in smokers and non-smokers.
Journal
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- BUNSEKI KAGAKU
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BUNSEKI KAGAKU 65 (12), 729-735, 2016
The Japan Society for Analytical Chemistry
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Details 詳細情報について
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- CRID
- 1390001204661176192
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- NII Article ID
- 130005286334
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- NII Book ID
- AN00222633
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- NDL BIB ID
- 027794091
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- ISSN
- 05251931
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed