Magnetic properties of Cu3(TeO3)2Br2 with spin 1/2 diamond lattice

  • Uematsu Daisuke
    Department of Physics, Division of Material Science, Nagoya University
  • Sato Masatoshi
    Department of Physics, Division of Material Science, Nagoya University

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タイトル別名
  • Magnetic Properties of Cu<SUB>3</SUB>(TeO<SUB>3</SUB>)<SUB>2</SUB>Br<SUB>2</SUB> with Spin 1/2 Diamond Lattice

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Magnetic studies have been carried out on Cu3(TeO3)2Br2 with diamond lattice of spin 1/2 Cu2+ ions. By using the high temperature expansion of the magnetic susceptibility, the exchange coupling constants have been determined to be J1kB=280±4 K (antiferromagnetic) and J2kB=−23±1 K (ferromagnetic) for two kinds of Cu–Cu pairs formed by the connections with edge and diagonal lines of a diamond, respectively. It indicates that each diamond chain has the ferrimagnetic state in the reported phase diagram [Takano et al.: J. Phys.: Condens. Matter 8 (1996) 6405]. The observed magnetic behavior can be well understood by this characteristic. Because J2 is ferromagnetic, the present system does not have magnetic frustration effects.

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