Molecular and Crystal Structures of Dicationic Tetrakis(1,3-benzodithiol-2-ylidene)cyclopentanone

• Masafumi Ueda

• Akimi Tahara

• Takashi Shirahata

• Yohji Misaki

Abstract

Molecular and crystal structures of dicationic tetrakis(1,3-benzodithiol-2-ylidene)cyclopentanone (1b), (1b2+)2(ReO4−)4(CH3CN)3(H2O)0.7, were successfully determined by X-ray single-crystal diffraction. It was suggested that two 1,3-dithiol-2-ylidenes adjacent to the carbonyl group were effectively conjugated with each other. The remaining two 1,3-dithiol-2-ylidenes, where two positive charges were mainly distributed, were considerably twisted from the central five-membered ring.

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 89 (12), 1500-1502, 2016-12

  Tokyo : Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1521699230606107776
• NII Article ID: 130005316172
• NII Book ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.20160271
• NDL BIB ID: 027787099
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I027787099
• Web Site: https://academic.oup.com/bcsj/article-pdf/89/12/1500/53346070/bcsj.20160271.pdf
• Text Lang: en
• NDL Source Classification:
  • ZP1(科学技術--化学・化学工業)
• Data Source:
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN