The Development of Novel C-H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules

• Kuninobu Yoichiro

  Graduate School of Pharmaceutical Sciences, The University of Tokyo

抄録

This personal account summarizes our recent progress in the development of C-H transformations. We achieved ortho-selective C-H borylation and silylation using Lewis acid-base interaction between two substrates, and meta-selective C-H borylation using hydrogen bonding between a hydrogen donor unit of a ligand and a substrate functional group. Regioselective C-H trifluoromethylation and related reactions of 6-membered heteroaromatic compounds were realized at the 2-, 4-, and benzylic-positions of the heteroaromatic rings. In addition, we developed C-H transformations directed towards the synthesis of organic functional materials, such as highly soluble polyimides and π-conjugated molecules containing either heteroatom(s) or a Lewis acid-base interaction.

収録刊行物

• 有機合成化学協会誌

  有機合成化学協会誌 74 (11), 1058-1068, 2016

  公益社団法人 有機合成化学協会

キーワード

• Organic Chemistry

詳細情報

• CRID: 1390282680316766976
• NII論文ID: 130005433327
• NII論文ID: 40021003091
• NII書誌ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.74.1058
• ISSN: 18836526
• ISSN: 00379980
• NDL書誌ID: 027740197
• Web Site: http://id.ndl.go.jp/bib/027740197
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I027740197
• Web Site: https://www.jstage.jst.go.jp/article/yukigoseikyokaishi/74/11/74_1058/_pdf
• 本文言語コード: en
• データソース種別:
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