High-magnetic-field X-ray absorption spectroscopy of field-induced valence transition in EuNi2(Si1-xGe[x])2

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  • High-Magnetic-Field X-ray Absorption Spectroscopy of Field-Induced Valence Transition in EuNi<SUB>2</SUB>(Si<SUB>1−<I>x</I></SUB>Ge<I><SUB>x</SUB></I>)<SUB>2</SUB>
  • High-Magnetic-Field X-ray Absorption Spectroscopy of Field-Induced Valence Transition in EuNi<sub>2</sub>(Si<sub>1-<i>x</i></sub>Ge<sub><i>x</i></sub>)<sub>2</sub>

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The magnetic-field-induced valence transition in EuNi2(Si1−xGex)2 (x=0.82, 0.85) has been studied by X-ray absorption spectroscopy at low temperatures. The field dependence of the Eu valence is directly observed for the first time. We find a significant decrease in the valences at high magnetic fields above 40 T. The valence of Eu changes from v*=2.75 at a zero field to v*=2.33 at 40 T for x=0.82. The results are analyzed using a theoretical model. The hybridization parameter V between the Eu2+ and Eu3+ states and the energy separation ΔE are determined, which are crucial for quantum mechanical mixing.

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