Magnetic excitations of NaxCoO2・yD2O: neutron scattering

  • Moyoshi Taketo
    Department of Physics, Division of Material Science, Nagoya University
  • Yasui Yukio
    Department of Physics, Division of Material Science, Nagoya University
  • Kobayashi Yoshiaki
    Department of Physics, Division of Material Science, Nagoya University
  • Sato Masatoshi
    Department of Physics, Division of Material Science, Nagoya University
  • Kakurai Kazuhisa
    Quantum Beam Science Directorate, Japan Atomic Energy Agency

書誌事項

タイトル別名
  • Magnetic Excitations of Na<I><SUB>x</SUB></I>CoO<SUB>2</SUB>·<I>y</I>D<SUB>2</SUB>O —Neutron Scattering—
  • Magnetic Excitations of Na<sub><i>x</i></sub>CoO<sub>2</sub>·<i>y</i>D<sub>2</sub>O –Neutron Scattering–

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抄録

In neutron inelastic measurements on aligned crystals of NaxCoO2·yD2O, two magnetic peaks have been observed. One peak corresponds to the contribution of ferromagnetic fluctuations and another peak, that of antiferromagnetic fluctuations. Both have two-dimensional characteristics. The intensity of ferromagnetic fluctuation decreases with decreasing temperature T and becomes inappreciable below 25 K. In contrast, antiferromagnetic fluctuation remains finite at 5 K. We have also carried out specific heat measurements on several samples with different values of the 59Co-nuclear quadrupole frequency (νQ) within the region 12.0<νQ3≅3νQ<12.9 MHz, where the superconducting, nonsuperconducting and superconducting phases appear in the transition temperature (Tc)–νQ3 phase diagram with varying νQ3, and found that the electronic specific heat coefficient γ does not change so significantly as to indicate a topological change of the Fermi surface with νQ. These results imply that hole pockets, the existence of which is suggested by band calculations near the K points in the reciprocal space, do not exist in the entire superconducting νQ3 region and support that the superconducting pair symmetry does not change with νQ3 in the phase diagram.

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