Magnetic properties of RCoGe3 (R: Ce, Pr, and Nd) and strong anisotropy of the upper critical field in non-centrosymmetric compound CeCoGe3

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  • Magnetic Properties of RCoGe<SUB>3</SUB> (R: Ce, Pr, and Nd) and Strong Anisotropy of the Upper Critical Field in Non-centrosymmetric Compound CeCoGe<SUB>3</SUB>

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We grew single crystals of RCoGe3 (R: La, Ce, Pr, and Nd) by the Bi-flux method, and studied the magnetic properties of PrCoGe3 and NdCoGe3 and the pressure-induced superconducting property of CeCoGe3. These compounds crystallize in a non-centrosymmetric tetragonal structure. PrCoGe3 and NdCoGe3 were found to be a paramagnet and an antiferromagnet with the Néel temperature TN=3.8 K, respectively. Crystalline electric field (CEF) schemes were proposed for PrCoGe3 and NdCoGe3. The magnetic property of a pressure-induced superconductor CeCoGe3 is highly different from those of PrCoGe3 and NdCoGe3, or a similar pressure-induced superconductor CeIrSi3. This was discussed in connection with the superconductivity of CeCoGe3. We clarified the upper critical field Hc2 for H||[001] and [100] by measuring the electrical resistivity under pressure P in magnetic fields: Hc2(0)\\simeq24 T for H||[001] and Hc2(0)\\simeq3.1 T for H||[100] at 0 K at P=7.1 GPa. A huge Hc2(0) value for H||[001] is a combined phenomenon between the Rashba-type antisymmetric spin–orbit interaction and the electronic instability, as observed in CeIrSi3.

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