Low-temperature Hydrogenation of Toluene by Electrolysis of Water with Hydrogen Permeable Palladium Membrane Electrode

  • Sato Takafumi
    Department of Material and Environmental Chemistry, Utsunomiya University
  • Takada Ayaka
    Department of Material and Environmental Chemistry, Utsunomiya University
  • Itoh Naotsugu
    Department of Material and Environmental Chemistry, Utsunomiya University

抄録

<p>Hydrogenation of toluene proceeded with hydrogen derived from the electrolysis of water with an electrical cell that a hydrogen permeable palladium membrane was the cathode. The hydrogenation occurred with selectively permeated hydrogen through the membrane in a catalytic layer at more than 313 K and the rate of hydrogenation increased with increasing temperature. This system was stable at least several hours and about a half of hydrogen produced by the electrolysis can be used for hydrogenation.</p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 46 (4), 477-480, 2017

    公益社団法人 日本化学会

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